{"id":125,"date":"2018-12-15T23:10:01","date_gmt":"2018-12-15T23:10:01","guid":{"rendered":"https:\/\/people.smu.edu\/46760177\/?page_id=125"},"modified":"2018-12-15T23:10:01","modified_gmt":"2018-12-15T23:10:01","slug":"research","status":"publish","type":"page","link":"https:\/\/groups.chem.cmu.edu\/garcia-bosch\/research\/","title":{"rendered":"Publications"},"content":{"rendered":"
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36) Trammell, Rachel, and Isaac Garcia-Bosch. \"Synthetic Copper Complexes as Cu-Dependent Monooxygenase Model Systems and Catalysts for Dioxygen Reduction and Water Oxidation.\" (2021<\/strong>).<\/span><\/p>\n

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35)\u00a0Wu, Tong, et al. \"Mononuclear and Dinuclear Copper Complexes of Tridentate Redox-active Ligands with Tunable H-bonding Donors: Structure, Spectroscopy and H+\/e-Reactivity.\" <\/span>Chemistry, an Asian journal<\/i>, 2021,<\/strong> 16<\/em>(12), 1608-1618. DOI:10.1002\/asia.202100286<\/a><\/p>\n

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34) Wu, T.; MacMillan, S. N.; Rajabimoghadam, K.; Siegler, M. A.; Lancaster, K. M.*; and Garcia-Bosch, I.* \u201cStructure, spectroscopy and reactivity of a mononuclear copper hydroxide complex in three molecular oxidation states\u201d. J. Am. Chem. Soc.<\/em>, 2020,<\/strong> 142<\/em>, 12265-12276. DOI:10.1021\/jacs.0c03867<\/a><\/p>\n

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33) Rajabimoghadam, K.; Darwish Y.; Bashir U.; Pitman, D.; Eichelberger S.; Siegler, M. A.; and Garcia- Bosch, I*. \u201cTunable intramolecular multicenter H-bonding interactions in first-row metal complexes bearing bidentate redox-active ligands\u201d. <\/span>J. Coord. Chem. <\/em>2019,<\/strong> 1335<\/span>.\u00a0<\/span>DOI:10.1080\/00958972.2019.1624728<\/a><\/p>\n

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32) Trammell, R.; D\u2019Amore, L; Cordova, A.; Polunin P.; Xie, N.; Siegler, M. A.; Belanzoni, P.; Marcel Swart, M.*; and Garcia-Bosch, I.* \u201cCopper-Directed Hydroxylation of sp<\/span>2 <\/span>and sp<\/span>3 <\/span>C-H Bonds\u201d. <\/span>Inorg. Chem. <\/em>2019<\/strong>,<\/strong> 58<\/em>, <\/span>7584<\/span>.DOI:<\/span>\u00a010.1021\/acs.inorgchem.9b00901<\/a><\/p>\n

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31} Trammell, R.; Rajabimoghadam, K.; and Garcia-Bosch, I.* \u201cCopper-Promoted Functionalization of Organic Molecules: from Biologically Relevant Cu\/O<\/span>2 <\/span>Model Systems to Organometallic Transformations\u201d. <\/span>Chem. Rev<\/em>., <\/span>2019,<\/strong> 119<\/em>, <\/span>2954.<\/span><\/p>\n<\/div>\n<\/div>\n<\/div>\n<\/div>\n

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\u00a030) Rajabimoghadam, K.; Darwish Y.; Bashir U.; Pitman, D.; Eichelberger S.; Siegler, M. A.; Swart, M.*; and Garcia-Bosch, I.* \u201cCatalytic Aerobic Oxidation of Alcohols by Copper Complexes Bearing Redox-Active Ligands with Tunable H-Bonding Groups\u201d. <\/span>J. Am. Chem. Soc<\/em>., <\/span>2018,<\/strong> 140<\/em>, 16625.DOI: 10.1021\/jacs.8b08748<\/a><\/span><\/p>\n

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\u00a029) Trammell, R.; See, Y. Y.; Herrmann, A. T.; Xie, N.; Di\u0301az, D. E.; Siegler, M. A.; Baran, P. S.; Garcia-Bosch, I.* \u201cDecoding the Mechanism of Intramolecular Cu-Directed Hydroxylation of sp<\/span>3 <\/span>C\u2013H Bonds\u201d. <\/span>J. Org. Chem<\/em>. <\/span>2017,<\/strong> 82<\/em>,<\/em> 7887. DOI: 10.1021\/acs.joc.7b01069<\/a><\/span><\/p>\n

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28) Garcia-Bosch, I.*, \"Copper-Catalyzed Oxidation of Alkanes under Mild Conditions\". Synlett<\/em>, 2017,<\/strong> 28<\/em>, 1237. (Synpacts Article).<\/p>\n<\/div>\n<\/div>\n<\/div>\n

DOI: <\/span>10.1055\/s-0036-1590202<\/a> (Synpacts Article).<\/p>\n

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27) Garcia-Bosch, I.*, Cowley, R. E.; Di\u0301az, D. E.: Peterson, R. L.: Solomon, E. I.*; and Karlin, K. D.* \u201cSubstrate and Lewis Acid Coordination Promote O\u2013O Bond Cleavage of an Unreactive L2CuII2(O22\u2013) Species to Form L2CuIII2(O)2 Cores with Enhanced Oxidative Reactivity.\u201d J. Am. Chem. Soc.<\/em>, 2017,<\/strong> 139,<\/em> 3186. Note: I.G.-B. affiliated with SMU. DOI:\u00a010.1021\/jacs.6b12990<\/a><\/span><\/p>\n

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26) Adam, S. M.; Garcia-Bosch, I., Schaefer A. W.; Sharma, S. K.; Siegler, M. A., Solomon, E. I.*; and Karlin, K. D.* \u201cCritical Aspects of Heme\u2013Peroxo\u2013Cu Complex Structure and Nature of Proton Source Dictate Metal\u2013Operoxo Breakage versus Reductive O\u2013O Cleavage Chemistry.\u201d <\/span>J. Am. Chem.<\/em> Soc.<\/em><\/span>, <\/em>2017,<\/strong> 139<\/em>,<\/em> 472. <\/span>Note: I.G.-B. affiliated with SMU.\u00a0DOI: 10.1021\/jacs.6b11322<\/a><\/span><\/p>\n

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25) Garcia-Bosch, I.*; Siegler, M. A. \"Copper-Catalyzed Oxidation of Alkanes with H<\/span>2<\/span>O<\/span>2 <\/span>under a Fenton-like Regime\". <\/span>Angew. Chem. Int. Ed., <\/em>2016,<\/strong> <\/span>55, <\/em>12873.\u00a0DOI: 10.1002\/anie.201607216<\/a><\/span><\/p>\n<\/div>\n<\/div>\n<\/div>\n

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24) Garcia-Bosch, I.<\/u>; Cowley, R. E.; D\u00edaz, D. E.; Siegler, M. A.; Nam, W.; Solomon, E. I. and Karlin, K.D. \u201cDioxygen Activation by a Macrocyclic Copper Complex Leads to a Cu2O2 Core with Unexpected Structure and Reactivity\u201d. Chem. Eur. J.<\/em>, 2016<\/strong>, 22<\/em>, 5133. DOI: 10.1002\/chem.201600551<\/a><\/p>\n

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23) Hematian, S.; Garcia-Bosch, I<\/u>.; and Karlin, K. D. \"Synthetic Heme\/Copper Assemblies: Toward an Understanding of Cytochrome c Oxidase Interactions with Dioxygen and Nitrogen Oxides\" Acc. Chem. Res.,<\/em> 2015<\/strong>, 48<\/em>, 2462. DOI: 10.1021\/acs.accounts.5b00265<\/a> Special issue \u201cSynthesis in Biological Inorganic Chemistry\u201d.<\/em><\/p>\n

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22) Serrano-Plana, J.; Garcia-Bosch, I.<\/u>; Company, A.; and Costas, M. \"Structural and Reactivity Models for Copper Oxygenases: Cooperative Effects and Novel Reactivities\". Acc. Chem. Res.,<\/em> 2015<\/strong>, 48<\/em>, 2397. DOI: 10.1021\/acs.accounts.5b00187<\/a>. Special issue \u201cSynthesis in Biological Inorganic Chemistry\u201d.<\/em><\/p>\n

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\u00a021) Garcia-Bosch, I.<\/u>; Adam, S. M.; Schaefer, A. W.; Sharma, S. K.; Peterson, R. L.; Solomon, E. I.; Karlin, K. D. 'A \u201cNaked\u201d FeIII-(O22\u2013)-CuII Species Allows for Structural and Spectroscopic Tuning of Low-Spin Heme-Peroxo-Cu Complexes' J. Am. Chem. Soc.<\/em> 2015<\/strong>, 137<\/em>, 1032. DOI: 10.1021\/ja5115198<\/a><\/p>\n

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20) Serrano-Plana, J.; Garcia-Bosch, I.<\/u>; Miyake, R.; Costas, M. and Company, A. \u201cSelective Ortho-Hydroxylation\u2013Defluorination of 2-Fluorophenolates with a Bis(\u03bc-oxo)dicopper(III) Species\u201d. Angew. Chem. Int. Ed<\/em>., 2014<\/strong>, 53<\/em>, 9608. DOI: 10.1002\/anie.201405060<\/a><\/p>\n

19) Lee, J. Y.; Peterson, R. L.; Ohkubo, K.; Garcia-Bosch, I.<\/u>; Himes, R. A.; Woertink, J.; Moore, C. D.; Solomon, E. I.; Fukuzumi, S.; and Karlin, K. D. \u201cMechanistic Insights into the Oxidation of Substituted Phenols via Hydrogen Atom Abstraction by a Cupric-Superoxo Complex\u201d. J. Am. Chem. Soc<\/em>., 2014<\/strong>, 136<\/em>, 9925. DOI: 10.1021\/ja503105b<\/a><\/p>\n

18) Lentini S.; Galloni, P.; Garcia-Bosch, I.<\/u>; Costas, M.; and Conte, V. \u201cIonic liquids as reaction media in catalytic oxidations with manganese and iron pyridyl triazacyclononane complexes\u201d. Inorg. Chim. Acta<\/em>, 2014<\/strong>, 410<\/em>, 60. DOI: 10.1016\/j.ica.2013.10.016<\/a><\/p>\n

17) Cuss\u00f3, O.; Garcia-Bosch, I.<\/u>; Font, D.; Ribas, X.; Lloret-Fillol, J.; and Costas, M. \u201cHighly Stereoselective Epoxidation with H2O2 Catalyzed by Electron-Rich Aminopyridine Manganese Catalysts\u201d Org. Lett.<\/em>, 2013<\/strong>, 15<\/em>, 6158. DOI: 10.1021\/ol403018x<\/a><\/p>\n

16) Garcia-Bosch, I.<\/u>; Sharma, S. K.; and Karlin, K. D. \u201cA Selective Stepwise Heme Oxygenase Model System: An Iron(IV)-Oxo Porphyrin \u03c0\u2011Cation Radical Leads to a Verdoheme-Type Compound via an Isoporphyrin Intermediate\u201d. J. Am. Chem. Soc.<\/em>, 2013<\/strong>, 135<\/em>, 16248. DOI: 10.1021\/ja405739m<\/a><\/p>\n

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15) Cuss\u00f3, O.; Garcia-Bosch, I.<\/u>; Ribas, X.; Lloret-Fillol, J.; and Costas, M. \u201cAsymmetric Epoxidation with H2O2 by Manipulating the Electronic Properties of Non-heme Iron Catalysts\u201d. J. Am. Chem. Soc.<\/em>, 2013<\/strong>, 135<\/em>, 14871-14878. DOI: 10.1021\/ja4078446<\/a><\/p>\n

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14) Codol\u00e0, Z.; Garcia-Bosch, I.<\/u>; Acu\u00f1a-Par\u00e9s, F.; Prat, I.; Luis, J. M.; Costas, M. and Lloret-Fillol, J. \u201cElectronic Effects on Single-Site Iron Catalysts for Water Oxidation\u201d. Chem. Eur. J.<\/em>, 2013<\/strong>, 19<\/em>, 8042. DOI: 10.1002\/chem.201301112<\/a><\/p>\n

13) Garc\u00eda-Sim\u00f3n, C.; Garcia-Borr\u00e0s, M.; G\u00f3mez, L.; Garcia-Bosch, I<\/u>.; Osuna, S.; Swart, M.; Luis, J. M.; Rovira, C.; Almeida, M.; Imaz, I.; Maspoch, D.; Costas, M.; and Ribas, X. \u201cSelf-Assembled Tetragonal Prismatic Molecular Cage Highly Selective for Anionic \u03c0 Guests\u201d. Chem. Eur. J.,<\/em> 2013<\/strong>, 19<\/em>, 1445. DOI: 10.1002\/chem.201203376<\/a><\/p>\n

12) Garcia-Bosch I.<\/u>; Codol\u00e0 Z.; Prat I.; Ribas X.; Lloret-Fillol J.; and Costas M. \u201cIron-Catalyzed C-H Hydroxylation and Olefin cis<\/em>-Dihydroxylation Using a Single-Electron Oxidant and Water as the Oxygen-Atom Source.\u201d Chem. Eur. J.<\/em>, 2012<\/strong>, 18<\/em>, 13269. DOI: 10.1002\/chem.201202147<\/a><\/p>\n

11) Garcia-Bosch, I.<\/u>, Ribas, X. and Costas, M. \u201cElectrophilic Arene Hydroxylation and Phenol O-H Oxidations Performed by an Unsymmetric \u03bc-\u03b71:\u03b71-O2-Peroxo-Dicopper(II) Complex.\u201d Chem. Eur. J.<\/em>, 2012<\/strong>, 18<\/em>, 2113. DOI: 10.1002\/chem.201102372<\/a><\/p>\n

10) Garcia-Bosch, I.<\/u>; G\u00f3mez, L.; Polo, A.; Ribas, X. and Costas, M. \u201cStereoselective Epoxidation of Alkenes with H2O2 Using Bipyrrolidine-Based Family of Manganese Complexes\u201d. Adv. Synth. Catal.<\/em>, 2012<\/strong>, 354<\/em>, 65. DOI: 10.1002\/adsc.201100409<\/a><\/p>\n

9) Garcia-Bosch I.<\/u>; Ribas X.; and Costas M. \u201cWell-Defined Heterometallic and Unsymmetric M2O2 Complexes Arising from Binding and Activation of O2\u201d Eur. J. Inorg. Chem.<\/em>, 2012<\/strong>, 179. DOI: 10.1002\/ejic.201100957<\/a><\/p><\/div>\n\t\t\t<\/div>

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Ph.D. (2008 - 2011)<\/strong><\/span><\/p><\/div>\n\t\t\t<\/div>

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8) Lloret, F.; Codol\u00e0, Z.; Garcia-Bosch, I.<\/u>; G\u00f3mez, L.; Pla, J. and Costas, M. \u201cEfficient Water Oxidation Catalyst Based on Readily Available Iron Coordination Complexes\u201d. Nat. Chem.<\/em>2011<\/strong>, 3<\/em>, 807. DOI: 10.1038\/nchem.1140<\/a><\/p>\n

7) Garcia-Bosch, I.<\/u>; Company, A.; Cady, C. W.; Styring, S.; Browne, W. R.; Ribas, X.; Costas, M. \"Evidence for a Precursor Complex in C-H Hydrogen Atom Transfer Reactions Mediated by a Manganese(IV) Oxo Complex\". Angew. Chem. Int. Ed., <\/em>2011<\/strong>, 50<\/em>, 5648. DOI: 10.1002\/anie.201100907<\/a><\/p>\n

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\n\t\t\t\t\n\t\t\t\t\n\t\t\t\t\n\t\t\t\t\n\t\t\t\t\"\"<\/span>\n\t\t\t<\/div>
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6) Garcia-Bosch, I.<\/u>; Company, A.; Frisch, J. R.; Cardellach, M; Sol\u00e0, M.; Gamba, I.; Casella, L.; Que, L. Jr.; Ribas, X. Luis, J. M. and Costas, M. \u201cO2 Activation and Selective Phenolate ortho-Hydroxylation by an Asymmetric Dicopper \u03bc-\u03b71:\u03b71-peroxido Complex\u201d. Angew. Chem. Int. Ed.,<\/em> 2010<\/strong>, 49<\/em>, 2406. DOI: 10.1002\/anie.200906749<\/a><\/p>\n

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5) Gomez, L.; Garcia-Bosch, I.<\/u>; Company, A.; Benet-Buchholz, J.; Polo, A.; Sala, X.; Ribas, X.; Costas, M. \u201cStereospecific C-H Oxidation with H2O2 Catalyzed by a Chemically Robust Site Isolated Iron Catalyst\u201d. Angew. Chem. Int. Ed.<\/em>, 2009<\/strong>, 48<\/em>, 5720. DOI: 10.1002\/anie.200901865<\/a><\/p>\n

4) Garcia-Bosch, I.<\/u>; Ribas, X. and Costas, M. \u201cA Broad Substrate-Scope Method for Fast, Efficient and Selective H2O2-Epoxidation\u201d. Adv. Synth. Catal.<\/em>, 2009<\/strong>, 351<\/em>, 348. DOI: 10.1002\/adsc.200800650<\/a><\/p>\n

3) Garcia-Bosch, I.<\/u>; Company, A.; Fontrodona, X.; Ribas, X. and Costas, M. \u201cEfficient and Selective Peracetic Acid Epoxidation Catalyzed by a Robust Manganese Complex\u201d. Org. Lett.<\/em>, 2008<\/strong>, 10<\/em>, 2095. DOI: 10.1021\/ol800329m<\/a><\/p>\n

2) Company, A.; Palavicini, S.; Garcia-Bosch, I.<\/u>; Mas-Ballest\u00e9, R.; Que, L. Jr.; Rybak-Akimova, E. V.; Casella, L.; Ribas, X. and Costas, M. \u201cTyrosinase-Like Reactivity in a CuIII2(\u03bc-O)2 Species\u201d. Chem. Eur. J.<\/em>; 2008<\/strong>, 14<\/em>, 3535. DOI: 10.1002\/chem.200800229<\/a><\/p>\n

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M. S. (2006 - 2007)<\/strong><\/span><\/p><\/div>\n\t\t\t<\/div>

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1) G\u00f3mez, L., Garcia-Bosch, I.<\/u>; Company, A.; Sala, X.; Fontrodona, X.; Ribas, X.; and Costas, M. \u201cChiral manganese complexes with pinene appended tetradentate ligands as stereoseletive epoxidation catalysts\u201d. Dalton Trans., <\/em>2007,<\/strong> 5539. DOI: 10.1039\/B712754E<\/a><\/p><\/div>\n\t\t\t<\/div>

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Book Chapters<\/strong><\/span><\/h4><\/div>\n\t\t\t<\/div>
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B) Garcia-Bosch, I.<\/u>; Karlin, K. In The Chemistry of Peroxides; Liebman, A. G. a. J. F., Ed.; John Wiley & Sons, Ltd: Chichester, UK, 2014<\/strong>; Vol. 3, 805. DOI: 10.1002\/9780470682531.pat0863<\/a><\/p>\n

A) Garcia-Bosch I.<\/u>; Prat, I.; Ribas, X.; and Costas, M. \u201cBioinspired Oxidations Catalyzed by Nonheme Iron and Manganese Complexes\u201d. In Innovative Catalysis in Organic Synthesis: Oxidation, Hydrogenation, and C-X Bond Forming Reactions. Ed. by Pher G. Andersson. Wiley-VCH Verlag GmbH&Co. KGaA. 2012<\/strong>, 27. DOI: 10.1002\/9783527646586.ch2<\/a><\/p><\/div>\n\t\t\t<\/div>

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Patents <\/strong><\/span><\/p><\/div>\n\t\t\t<\/div>

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iii) Company, A.; Font, D.; Prat, I.; G\u00f3mez, L.; Ribas, X.; Garcia-Bosch, I.; Costas, M.; Lloret-Fillol, J.; and Cuss\u00f3, O. Title: \u201cCatalysts for the epoxidation of alkenes\u201d. Spain Application N\u00ba ES 2012-31746. Date of priority: 13th November 2012<\/strong>.<\/p>\n

ii) Codol\u00e0, Z.; G\u00f3mez, L.; Garcia-Bosch, I.; Pla Aicart, J. J.; Lloret, J.; and Costas, M. Title: \u201cProcedure for the catalytic oxidation of water with iron catalysts\u201d. Spain Application N\u00ba ES 2011-31147. Date of priority: 6th July 2011<\/strong>.<\/p>\n

i) Costas, M.; Ribas, X.; Garcia-Bosch, I.; Company, A.; and G\u00f3mez, L. Title: \u201dManganese catalysts and their use for the selective epoxidation of olefins\u201d. Spain. N\u00ba ES 2008-1081. Date: 10th April 2008<\/strong>.<\/p><\/div>\n\t\t\t<\/div>\n\t\t\t<\/div>\n\t\t\t\t\n\t\t\t\t\n\t\t\t\t\n\t\t\t\t\n\t\t\t<\/div>\n\t\t\t\t\n\t\t\t\t\n\t\t\t<\/div>\n","protected":false},"excerpt":{"rendered":"","protected":false},"author":8,"featured_media":0,"parent":0,"menu_order":0,"comment_status":"closed","ping_status":"closed","template":"","meta":{"_et_pb_use_builder":"on","_et_pb_old_content":"","_et_gb_content_width":"","footnotes":""},"class_list":["post-125","page","type-page","status-publish","hentry"],"_links":{"self":[{"href":"https:\/\/groups.chem.cmu.edu\/garcia-bosch\/wp-json\/wp\/v2\/pages\/125","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/groups.chem.cmu.edu\/garcia-bosch\/wp-json\/wp\/v2\/pages"}],"about":[{"href":"https:\/\/groups.chem.cmu.edu\/garcia-bosch\/wp-json\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"https:\/\/groups.chem.cmu.edu\/garcia-bosch\/wp-json\/wp\/v2\/users\/8"}],"replies":[{"embeddable":true,"href":"https:\/\/groups.chem.cmu.edu\/garcia-bosch\/wp-json\/wp\/v2\/comments?post=125"}],"version-history":[{"count":0,"href":"https:\/\/groups.chem.cmu.edu\/garcia-bosch\/wp-json\/wp\/v2\/pages\/125\/revisions"}],"wp:attachment":[{"href":"https:\/\/groups.chem.cmu.edu\/garcia-bosch\/wp-json\/wp\/v2\/media?parent=125"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}